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By analogy, 5 was most likely a glutathionylated derivative of grossamide K (Table 1 and Figure 4), which consists of feruloyltyramine condensed with coniferyl alcohol ( 6 appeared to be a glutathionylated derivative of the condensate of feruloyltyramine with hydroxyconiferyl alcohol (Table 1 and Figure 4)

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Surprisingly, PSC was not mentioned by the illustrious British surgeon of his day, Lord Edwin Rodney Smith KBE, FRCS, Baron of Marlow, ‡ in his 1964 definitive textbook on biliary surgery